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Differences in the concentration of a component result in a net difference in the Gibbs free energy of the molecules of that component in the more concentrated region and the more dilute region. That difference provides a driving force for the molecules in the more concentrated region to migrate towards the more dilute region while there is less driving force for the molecules in the dilute region to migrate against the gradient, resulting in a net effect of diffusion. Note that if the Gibbs free energy can be raised in one region compared to another by some other means, such as increasing the pressure on one side of a membrane, you can actually get diffusion against the concentration gradient. That's how reverse osmosis works.

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7y ago

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