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An interesting question and a complicated one to answer. You will have to do some reading and understand the basics of nuclear reactions, to be able to grasp the details. The main difference between stars of the sun's size and larger stars is the temperature of the interior and this makes different reactions predominate. In the sun it is the proton-proton reaction which is most important. In larger stars with higher temperatures a more complicated chain results which includes a carbon-nitrogen-oxygen cycle. In both cases the starting point is nuclei of hydrogen and the end point is nuclei of helium, with energy being released.

You can find out more in Wikipedia entries 'Proton-proton chain reaction' and 'CNO cycle', but be warned, you will have to concentrate hard!

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