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One approach would be to reduce nickel oxide in a hydrogen stream.

Alternatively, one could oxidize NiS on an oxygen stream to get rid of the volatile sulfur.

An alternative approach would be to electrowin the metal from an acid solution, i.e. by electroplating.

If you required very high purity Ni, then zone refiningof a cylindrical sample will produce very pure metal.

[For example, high purity Tantalum, 99.999%, may be produced by this method.]

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