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If the water coolant level drops enough to expose fuel rods, the surface of those rods can then get hotter than the boiling point of water. The fuel pellets inside the rods are clad in zirconium metal, which when it gets hot enough will decompose water (both as liquid and as steam) into hydrogen and oxygen. As the hydrogen is lighter than air it accumulates as a "bubble" in the top of the reactor vessel.

Note: early reactors clad the fuel pellets with aluminum, but it decomposes water at a much lower temperature than does zirconium.

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