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Water evaporate because the sun heats it up and it turns into water vapor .

There are three classical states of matter; solid, liquid, and gas. All matter can go through these states. When matter is a solid that means the matter has a fixed shape and volume. A liquid state is when matter has no fixed shape but a definite volume. A gas state is achieved when matter has no volume or shape. Typically matter becomes a solid when it reaches it's freezing point. Matter becomes a liquid at the melting point. A gas forms when a substance reaches it's boiling point. Vapor is when a substance is in it's gas form while being under it's critical temperature; vapors unlike gases can return to a liquid or solid state without changing it's temperature. Now every chemical has different points for it's states of matter. Water turns to solid below 32 F (0 C), a liquid between 32-212 F (0-100 C), and becomes a gas at 212 F (100 C) and above.

To answer your question, water can evaporate because like all substances, water slowly vaporizes or "reverse condensates" (liquid -> gas).

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