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Radiation can involve gamma rays, X-Rays, alpha particles and beta partcles. In terms of molecules these are termed ionizing radiation but they both ionize and break bonds to produce radicals.

Ionizing radiations effect on water is to produce hydrogen peroxide, hydrogen, oxygen, ozone, . The pathways are complex involving the breakdown of water molecules into positively charged radicals, such as H2O+, neutral radicals OH and H and solvated electrons. Chain reactions coupled with reionization of some of the "initial" products makes for a complex situation.

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