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The process is called photochlorination of a hydrocarbon. It is messy and dangerous. The mechanism proceeds through free radical intermediates. The Cl2 molecule is cleaved via ultraviolet light or intense heat into two .Cl free radicals, which go on to react with the methane (or whatever alkane you desire).

The process can be difficult to control however due to the seemingly limitless number of byproducts formed. These byproducts can include polyhalogenated alkanes and alkanes larger than the one you started with. The latter occurs through abstraction and combination of alkyl radicals.

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16y ago

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