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Rust is the oxidation of iron.

Metals will react with oxygen but only iron'rusts'.

Aluminium oxidises but it forms an impermeable oxide layer on the aluminum which prevents further oxidation.

Zinc has a stronger affinity for oxygen than iron. Zinc is used to coat iron in a process known as galvanising. The zinc oxidises preventing the iron from rusting. The zinc actually forces the iron to keep its electrons rather than losing them to oxygen.

2Fe(s) + 3O2(g) --> 2Fe2O3(s)

2Zn(s) + O2(g) --> 2ZnO(s)

When iron and zinc are together:

Zn(s) + Fe2+ --> Zn2+ + Fe(s)

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