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One pound is 0.4536 kg. 44g is the molar mass of CO2, so:

44 g contain the Avogadro number of carbon atoms, 6.023 x 10^23

so 1 g contains 6.023/44 x 10^23 atoms

1 kg contains 6.023/44 x 10^26 atoms

0.4536 kg contain 6.023 x 0.4536/44 x 10^26 atoms

= 6.209 x 10^24 atoms.

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