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From the Periodic Table, Argon has an atomic weight of 39.948. One mole of any element is equal to its atomic weight in grams. So 1 mole of Ar = 39.948g of Ar.

Using that equality, you do the following calculation to find the number of moles of Ar in 22g of Ar:

22g Ar X 1mol Ar/39.948g Ar = 0.55mol Ar

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