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The volt is not a unit of measure of energy. It is a unit of electromotive force (analogous to pressure in a pipe) or of electric potential difference (analogous to a difference in height). Energy is measured in joules.

An average lightning bolt carries about 500 megajoules of energy and transfers a charge of about 5 Coulombs with a current of about 30 kiloamperes. The voltage involved is proportional to the length of the lightning bolt and so is different for each one.

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