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I don't know as far as ELEMENT, however, ceramic is used in high heat engines, exhaust stacks, and furnaces for a reason. Also, space shuttles use ceramic or porcelain to re-enter the earths atmosphere witch to take the heat as its breaks through the atmosphere. If you are looking for metals, there are different types and even coated metals.

answ2. As far as thermal conductivity is concerned, graphene and diamond top the list.

Graphene 4800 - 5300, Diamond 1000 - 2000, Silver, 429, copper 401.

The units are in W.m-1.K-1.

Diamond is used as a heat sink under some microprocessors. Maybe to be overtaken by graphene.

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