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No, the atom is the basic unit for elements. An element consists of one type of atom; iron consists of iron atoms, sulfur consists of sulfur atoms, and so on. A Molecule is a group of atoms of one or more types; carbon dioxide (CO2) is a molecule consisting of one carbon atom and two oxygen atoms, water (H2O) consists of two hydrogen atoms and one oxygen atom. The molecule is the base unit for chemical compounds. A single molecule of water is still the chemical compound water, but if that molecule is split apart into its constituent parts, say through electrolysis, then it ceases to be water and becomes the two elements oxygen and hydrogen.

To be thorough, it is important to note that some elements occur naturally in molecular forms. Many gasses occur in molecules consisting of pairs of the same atoms: Hydrogen (H2), Oxygen (O2), Nitrogen (N2), for example. So why isn't the hydrogen molecule the base unit for the element hydrogen? The reason is that if you split the hydrogen molecule into its constituent atoms, those atoms still remain as hydrogen.

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