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This is simply because the evaporation enthalpy is bigger than the enthalpy of fusion. ΔTf = -Kf · m (m= molality) ΔTb = Kb · m (m= molality) what is important is that Kf is proportional to 1/Enthalpy of fusion and the sam is true for Kb (with enthalpy of evaporation)

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17y ago

What else can I help you with?