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Liquid may change into a vapor below the liquid's boiling point (or solid into vapor below the freezing point, think shrinking ice-cubes).

This is a very difficult phenomanon the explain.

The second law of thermodynamics explains that at every moment, the ammount of randomness of all matter in the universe is increasing. This randomness is called entropy. Entropy is a property of matter. The greater the number of locations and positions any given atom may randomly occupy at any given time, the greater that atom's entropy.

This is to say that the molecules in a liquid would prefer to be in the vapor phase because it would increase their entropy. However, they're held down in the liquid phase because of the inter-molecular forces they experience between one another.

If their temperature were higher, they would have enough energy (velocity) to escape the liquid phase. Luckily, at a given temperature, not every molecule has the same kinetic energy. There is actually a distribution of velocities (Maxwell-Boltzman distribution). The molecules having a high velocity manage to escape the intermolecular forces of the liquid phase and escape into the vapor phase.

The higher energy molecules escaping the liquid phase decreases the average molecular velocity and causes the liquid temperature to decrease. This is why you feel cold after you get out of the shower. Your body heat is transferred to the water molecules which then evaporate

The closer a liquid is to its boiling point, the greater the number of molecules there are that have enough kinetic energy to overcome the intermolecular forces and escape into the vapor phase, thus the higher the rate of evaporation.

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15y ago

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