The boiling point of hexane is 68 degrees Celsius, while the boiling point of butanol is 117.4 degrees Celsius. There is a difference of 49.4 degree Celsius between their boiling points.
The boiling point of any compound is determined by how much energy it takes to break apart the intermolecular bonds. C6H14 has very low intramolecular forces compared to the polar bonds of another compound, such as water.
The boiling point of benzene is about 80 0C while that of hexane is 69 0C, so Hexane is more volatile.
n-hexane is the unbranched alkane C6H14. All the bonds in the molecule are covalent. the bonds between the molecules are the weak London dispersive forces, n-hexane has a melting point of around -96 0C and a boiling point of around 68 0C.
Because Chloropropane is an alkane but tert-butyl alcohol is an alcohol. The O-H bond is much more difficult to break than the C-H bonds in the hydrocarbons that make up chloropropane. O-H bonds need more energy to break them; therefore the tert-butyl alcohol has a higher boiling point than chloropropane.
the polar molecule has a higher boiling point
Octane. The boiling point of straight-chain alkanes increases within its homologous series (meaning methane has a lower boiling point than ethane, which is lower than propane, etc). Hexane : Boiling Point 69 o C Octane : Boiling Point 125.5 o C
Boiling point of 1-butanol: 118 0C Boiling point of diethyl ether: 34,6 0C
2-butanol, also known as sec-butanol has a boiling point range from 98 to 100 degrees Celsius. The melting point is set at -115 degrees Celsius.
Methanol
The boiling point of any compound is determined by how much energy it takes to break apart the intermolecular bonds. C6H14 has very low intramolecular forces compared to the polar bonds of another compound, such as water.
The boiling point of benzene is about 80 0C while that of hexane is 69 0C, so Hexane is more volatile.
Think in terms of room temperature. Hexane is a liquid that is flammable, but is used in cleaning solvents and stuff like around the garage. Propane is the gas that comes in a steel bottle that you use for gas stoves and barbeque grills. So if you let propane out into the room its a gas and so it already past its boiling point. So the boiling point of Hexane is hotter than room temperature and the boiling point of propane is lower than room temperature. The actual numbers are 69 C and -42 C.
you can use the Clausius-Clapeyron equation if you know the temperature of hexane at 1.5 ATM
what is the difference between freezing and boiling point
Diethyl ether, and 1-butanol are similar in size (number of electrons), therefore, their boiling points will be determined by polarity. Diethyl ether has two polar C-O bonds. 1-butanol also has two polar bonds (C-O and O-H), but the O-H bond is more polar than the C-O bond, making 1-butanol more polar than diethyl ether and giving it a higher boiling point. Diethyl ether has weaker intermolecular forces of attraction and therefore a lower boiling point.
difference between critical temp and boiling point
Boiling Point Elevation