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I assume you are referring to valence electrons (the "outermost" shell varies widely in the number of electrons it can hold, the valence electrons are a subset of this which are responsible for chemical bonding and reactivity).

The number of valence electrons can only be from 1 electron to 8 electrons, these are divided between the s and p orbitals of a shell (each orbital can hold no more than 2 electrons).

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