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Starch is a polysaccharide (a polymer composed of monosaccharides linked by glycosidic bonds) composed of alpha-D-glucose bonded by 1,4 glycosidic bonds in its amylose form, which is a linear chain, and both 1,4 and 1,6 glycosidic bonds in amylopectin, its branched form.

In short: its monomer is alpha-D-glucose.

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