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Characteristics of Coal

The characteristics of coals that determine classification and suitability for given applications are the proportions of :

1. volatile matter

2. fixed carbon

3. moisture

4. sulfur

5. ash

Each of these is reported in the proximate analysis. Coal analyses can be reported on several bases: as-received, moisture-free (or dry), and mineral-matter-free (or ash-free). As-received is applicable for combustion calculations; moisture-free and mineral-matter-free, for classification purposes.

Volatile matter is driven off as gas or vapor when the coal is heated according to a standard temperature test. It consists of a variety of organic gases, generally resulting from distillation and decomposition. Volatile products given off by coals when heated differ materially in the ratios (by mass) of the gases to oils and tars. No heavy oils or tars are given off by anthracite, and very small quantities are given off by semianthracite. As volatile matter in the coal increases to as much as 40% of the coal (dry and ash-free basis), increasing amounts of oils and tars are released. However, for coals of higher volatile content, the quantity of oils and tars decreases and is relatively low in the subbituminous coals and in lignite.

Fixed carbon is the combustible residue left after the volatile matter is driven off. It is not all carbon. Its form and hardness are an indication of fuel coking properties and, therefore, guide the choice of combustion equipment. Generally, fixed carbon represents that portion of fuel that must be burned in the solid state.

Moisture is difficult to determine accurately because a sample can lose moisture on exposure to the atmosphere, particularly when reducing the sample size for analysis. To correct for this loss, total moisture content of a sample is customarily determined by adding the moisture loss obtained when air-drying the sample to the measured moisture content of the dried sample. Moisture does not rep-resent all of the water present in coal; water of decomposition (combined water) and of hydration are not given off under standardized test conditions.

Ash is the noncombustible residue remaining after complete coal combustion. Generally, the mass of ash is slightly less than that of mineral matter before burning. Sulfur is an undesirable constituent in coal, because the sulfur oxides formed when it burns contribute to air pollution and cause combustion system corrosion.

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12y ago

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