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well temp., pressure, volume, and mass

Measurable Properties of Gases(1) The characteristics of gases are described fully in terms of four parameters or measurable properties :

(i) The volume, V, of the gas.

(ii) Its pressure, P

(iii) Its temperature, T

(iv) The amount of the gas (i.e., mass or number of moles).

(2) Gas Volume : (i) Since gases occupy the entire space available to them, the measurement of volume of a gas only requires a measurement of the container confining the gas.

(ii) Volume is expressed in litres (L), millilitres (mL) or cubic centimetres (cm3) or cubic metres (m3).

(iii) 1 L = 1000mL; 1 mL = 10--3; 1 L = 1 dm3 = 10--3 m3

1 m3 = 103 dm3 = 106cm3 = 106mL = 103L

(3) Gas Mass : (i) The mass of a gas can be determined by weighing the container in which the gas is enclosed and again weighing the container after removing the gas. The difference between the two weights gives the mass of the gas.

(ii) The mass of the gas is related to the number of moles of the gas i.e.

moles of gas (n) = Mass in grams/Molar mass = m/M

(4) Temperature : (i) Gases expand on increasing the temperature. If temperature is increased twice, the square of the velocity (v2) also increases two times.

(ii) Temperature is measured in centigrade degree (oC) or celsius degree with the help of thermometers. Temperature is also measured in Fahrenheit (Fo).

(iii) S.I. unit of temperature is kelvin (K) or absolute degree.

K = oC + 273

(iv) Relation between F and oC is oC/5 = Fo--32/9

(5) Pressure : (i) Pressure of the gas is the force exerted by the gas per unit area of the walls of the container in all directions. Thus, Pressure (P) = Force(F)/Area(A) = Mass(m)×Acceleration(a)/Area(a)

(ii) Pressure exerted by a gas is due to kinetic energy (KE = 1/2 mv2) of the molecules. Kinetic energy of the gas molecules increases, as the temperature is increased. Thus, Pressure of a gas ∝ Temperature (T).

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