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The carboxylic acid group may be detectable using FTIR which transmits through the sample. ATR-IR may provide a surface concentration. Of course, a calibration with known amounts of PAA would need to be prepared in advance in order to measure quantitatively. Titrating the acid group may be another option. If the PAA content is high, the product may swell in water more than at low concentrations. This may be an indirect method.

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