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The friction strike anywhere match has active ingredients in the match head of phophorus sesquisulfide, P4S3 (which initiates combustion) and potassium chlorate as an additional oxidant.

The safety match has red phosphorus (allotrope of phosphorus) on the box with abrasive and binding agents, and potassium chlorate in the head with various binders.

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The matchstick burns when rubbed on the side of the matchbox due to the friction generated between the match head and the rough surface. This friction produces enough heat to ignite the chemicals in the match head, which typically contain an oxidizing agent and a combustible substance. The ignition starts a combustion reaction, resulting in the flame. The side of the matchbox is coated with a material that facilitates this reaction, enhancing the match's ability to ignite easily.


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Why does the match stick burn on rubbing it on the side of match box?

The matchstick burns when rubbed on the side of the matchbox due to the friction generated between the match head and the rough surface. This friction produces enough heat to ignite the chemicals in the match head, which typically contain an oxidizing agent and a combustible substance. The ignition starts a combustion reaction, resulting in the flame. The side of the matchbox is coated with a material that facilitates this reaction, enhancing the match's ability to ignite easily.


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