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if H and S are both negative

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Marielle Crist

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3y ago

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How will the temperature affect the spontaneity of a reaction with positive h and s?

A high temperature will make it spontaneous.


On what conditions does a spontaneous reaction become spontaneous?

For some non-spontaneous reactions, you can change the temperature. For other non-spontaneous reactions, there is nothing you can do to make it spontaneous. Nature favors reactions that increase a system's entropy (disorder) and nature favors reactions that are exothermic (they release enthalpy). Any reaction that does both of these things is spontaneous at all temperatures. Any reaction that does neither of these things is never spontaneous. As far as this question is concerned, the interesting reactions are endothermic reactions that increase entropy and exothermic reactions that decrease entropy. Whether these reactions are spontaneous depends on the temperature. The first variety (endothermic, increase entropy) will be spontaneous at high temperatures; the second (exothermic, decrease entropy) will be spontaneous at low temperatures. To find the temperature at which a reaction becomes spontaneous, one may apply the Gibbs equation: DG = DH - TDS where capital Ds stand for the Greek capital delta.


When is a reaction always spontaneous according to Gibbs free energy equation?

A reaction is always spontaneous when the change in Gibbs free energy (ΔG) is negative (ΔG < 0). This occurs when the system's enthalpy change (ΔH) is negative and the entropy change (ΔS) is positive, or when the temperature is sufficiently low to make the term TΔS (where T is temperature) less significant compared to ΔH. In summary, spontaneous reactions can be identified by a negative ΔG value, indicating that they can occur without external input.


How will temperature affect the spontaneity of a reaction positive delta h and delta s?

∆G = ∆H - T∆S and for it to be spontaneous, ∆G should be negative. If both ∆H and ∆S are positive, in order to get a negative ∆H, the temperature needs to be elevated in order to make the ∆S term greater than the ∆H term. So, I guess the answer would be "the higher the temperature, the more likely will be the spontaneity of the reaction."


How will temperature affect the spontaneity of a reaction with positive delta h and delta s?

For a reaction with a positive enthalpy change (ΔH > 0) and a positive entropy change (ΔS > 0), temperature plays a crucial role in determining spontaneity. The Gibbs free energy change (ΔG) is given by the equation ΔG = ΔH - TΔS. As temperature increases, the TΔS term becomes larger, which can help make ΔG negative, thus favoring spontaneity. Therefore, at sufficiently high temperatures, the reaction can become spontaneous despite the positive ΔH.

Related Questions

Under what conditions will a low temperature make a reaction spontaneous?

if H and S are both negative


How will the temperature affect the spontaneity of a reaction with positive h and s?

A high temperature will make it spontaneous.


When Could A High Temperature Make A Reaction That Was Nonspontaneous At Low Temperature Spontaneous?

A high temperature can make a nonspontaneous reaction spontaneous by providing enough energy to overcome the activation energy barrier, allowing the reaction to proceed. At low temperatures, the kinetic energy of the molecules may not be sufficient for them to react, but increasing the temperature can provide the necessary energy for the reaction to occur spontaneously.


According to the Gibbs free energy equation G H - T S when could a high temperature make a reaction that was nonspontaneous at low temperature spontaneous?

A high temperature could make a reaction spontaneous that was nonspontaneous at low temperature when the increase in entropy due to the reaction outweighs the increase in enthalpy. At higher temperatures, the TΔS term in the Gibbs free energy equation becomes more dominant, leading to a positive ΔG becoming negative, thus making the reaction spontaneous.


On what conditions does a spontaneous reaction become spontaneous?

For some non-spontaneous reactions, you can change the temperature. For other non-spontaneous reactions, there is nothing you can do to make it spontaneous. Nature favors reactions that increase a system's entropy (disorder) and nature favors reactions that are exothermic (they release enthalpy). Any reaction that does both of these things is spontaneous at all temperatures. Any reaction that does neither of these things is never spontaneous. As far as this question is concerned, the interesting reactions are endothermic reactions that increase entropy and exothermic reactions that decrease entropy. Whether these reactions are spontaneous depends on the temperature. The first variety (endothermic, increase entropy) will be spontaneous at high temperatures; the second (exothermic, decrease entropy) will be spontaneous at low temperatures. To find the temperature at which a reaction becomes spontaneous, one may apply the Gibbs equation: DG = DH - TDS where capital Ds stand for the Greek capital delta.


What factor might make an endothermic reaction spontaneous?

An endothermic reaction can be spontaneous if the increase in entropy (disorder) of the system is large enough to overcome the energy input required for the reaction to occur.


How will temperature affect the spontaneity of reaction with positive H and S?

A high temperature will make it spontaneous.


How do you make a sentence by using the word Spontaneous?

There was a spontaneous reaction of elation when the local lottery syndicate won one million pounds.


What is the reaction in a fuel cell spontaneous and non spontaneous?

Spontaneous ...Happens all by itself; typically unpredictableNon-spontaneous...You have to do something to make it happen.


When is a reaction always spontaneous according to Gibbs free energy equation?

A reaction is always spontaneous when the change in Gibbs free energy (ΔG) is negative (ΔG < 0). This occurs when the system's enthalpy change (ΔH) is negative and the entropy change (ΔS) is positive, or when the temperature is sufficiently low to make the term TΔS (where T is temperature) less significant compared to ΔH. In summary, spontaneous reactions can be identified by a negative ΔG value, indicating that they can occur without external input.


How will temperature affect the spontaneity of a reaction with positive triangle H and triangle S?

For a reaction with a positive enthalpy change (ΔH > 0) and a positive entropy change (ΔS > 0), the spontaneity is influenced by temperature through the Gibbs free energy equation: ΔG = ΔH - TΔS. As temperature increases, the TΔS term becomes larger, which can make ΔG more negative, thereby favoring spontaneity. Therefore, at higher temperatures, the reaction is more likely to be spontaneous, while at lower temperatures, it may not be spontaneous.


Why a spontaneous chemical reaction is not necessarily a fast reaction?

No. A spontaneous reaction is one that will happen given enough time - it doesn't need any energy or enzyme to make it happen. For instance, the decomposition of carbonic acid (H2CO3) into water and carbon dioxide (H2O and CO2) is spontaneous. However, it can be reversed by an enzyme called carbonic anhydrase; it just takes energy.