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Relative Standard Deviation (RSD) is a measure of precision (not accuracy). RSD is sometimes called coefficient of variation (CV) and often is calculated as a percentage. s = standard deviation x = mean RSD = s/x, as a percentage, (s/x) *100 The RSD allows standard deviations of different measurements to be compared more meaningfully. For example, if one is measuring the concentration of two compounds A and B and the result is 0.5 (+/-) 0.4 ng/mL for compound A and 10 (+/-) 2 ng/mL for compound B, one may look at the standard deviation for compound A and say because it is lower (0.4 vs. 2) than for B, the measurement for A was more precise. Actually this is not the case. When the %RSD is used the new values for compound A and B are 0.5 (+/-) 80% and 10 (+/-) 20% respectively, therefore, the measurement for compound B is more precise.

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