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The red-colored α, β and γ forms are produced from solutions of black selenium by varying evaporation rates of the solvent (usually CS2). They all have relatively low, monoclinic crystal symmetries and contain nearly identical puckered Se8 rings arranged in different fashions, as in sulfur. The packing is most dense in the α form. In the Se8 rings, the Se-Se distance is 233.5 pm and Se-Se-Se angle is 105.7 degrees. Other selenium allotropes may contain Se6 or Se7 rings.

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