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The element at the top of a group in the Periodic Table is typically the lightest and often the most reactive within that group. For example, in Group 1, hydrogen is at the top, while lithium is the first alkali metal. The properties of these elements can vary significantly from those lower in the group due to differences in atomic size and shielding effects. Generally, elements at the top tend to have higher electronegativities and ionization energies compared to their heavier counterparts.

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