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The elements from group 1-13 or IA-IIIA (including all of the B groups) tend to form cations.

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A cation is an element or molecule with a positive charge. This means that the element or molecule has lost one of its original electrons, making it less negative and therefore more positive.

So elements that have an affinity to give away their electrons tend to form cations. In order for elements to want to give away their electrons the process must be favorable... The most favorable process is when an element ends up with a full valence octet. Elements with more than half their valence electrons end up with a full octet by gaining more electrons whereas elements with fewer than half their valence electrons end up with a full octet by losing their outermost valence electrons therefore becoming cations.

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