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Depending on the energy of the alpha, fusion into Californium-246 could happen, or elastic Rutherford scattering could happen. If the alpha was energized enough to compensate for the reactions net mass increase (mCf - mCm - mα = 6.86MeV) and the Coulomb barrier (about 26MeV), so about 33MeV total, it could fuse into Cf246. Otherwise it'll bounce off the Cm242 via elastic scattering.

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