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The atomic weight (not mass !) of an element is the weighted average mass of the naturally occurring isotopes.Example: the atomic weight of chlorine is 35.45. Chlorine is naturally composed of chlorine-35 at 75.76% and the rest chlorine-37. Therefore, the mass of any sample must be due to (75.76 x 35 + 24.14 x 37)/100

The mass number of an element is the number of protons and neutrons of that isotope added together. In the above example there were two isotopes, one had a mass number of 35 and the other 37. Chlorine has 17 protons, so it is easy arithmetic to calculate the number of neutrons in each isotope.

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