Barium Nitride is the name for Ba3N2. It is a ceramic that can be used to dope down some white-light-emitting LEDs.
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Ba3O2 is the chemical formula for barium peroxide. It is a compound composed of three barium atoms and two oxygen atoms. Barium peroxide is a white solid that is used as a strong oxidizing agent and in the production of hydrogen peroxide.
There is no compound with this formula. You may have it confused with BaO, which is Barium oxide, or BaO2, which is Barium peroxide.