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The Question's last part is not precisely stated, but an answer could be something like this:

  1. ZnCO3 ==> ZnO + CO2 ................followed by:
  2. 2 ZnO + C ==> 2 Zn + CO2 ..........giving the overall reaction:
  3. 2 ZnCO3 + C <=> 2 Zn + 3 CO2 ..in which ZnO is balanced out.
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Balanced word equation for copper carbonate and hydrochloric acid?

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