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It is a chamber that consits of no particles and its inside, therefore, is a vaccum. (Get it? Evacuated > Vaccum).The volume inside of an evacuated chamber is zero and is used so an experiment conducted inside of it has little risk of being effected by particles. So in Rutherford's experiment, they use it so no gas particles/atoms/nuclei can get in the way of the alpha radiation which gets absorbed by the air after 5cm of travel and has such a large size and mass so the experiment has big chance of being affected by air particles.

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x BBC Merlin Fan

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