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Hess's Law states that the total enthalpy change for a chemical reaction is the same, regardless of the pathway taken, provided the initial and final states are the same. This principle allows for the calculation of the enthalpy change of a desired reaction by using the enthalpy changes of multiple intermediate reactions that add up to the overall reaction. By summing these known enthalpy changes, one can derive the enthalpy of the target reaction, even if it cannot be measured directly. This makes Hess's Law a valuable tool in thermochemistry for determining reaction enthalpies.

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