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HF orbital notation refers to the representation of the molecular orbitals in the hydrogen fluoride (HF) molecule. In this notation, the bonding molecular orbital is formed by the overlap of the hydrogen 1s orbital and the fluorine 2p orbital, resulting in a sigma bond. The notation helps visualize the distribution of electrons in the molecule, indicating that the bonding pair is primarily located around the fluorine atom due to its higher electronegativity. Thus, HF exhibits polar characteristics with a significant dipole moment.

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