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Intrinsic regulation is when the products of the reaction regulate the rate of the reaction, acting as regulators (usually allosteric) . i.e it is self-limiting.

Pyruvate + CoASH + NAD+ --> Acetyl-CoA + NADH2 + CO2

This is an example of the bridging reaction wherein pyruvate reacts with CoA and NAD+ to form Acetyl-Coa. The intrinsic regulator here is Acetyl-Coa as if it increases in concentration it inhibits the reaction (following Le Chateliers principle).

NADH2 is also an INTRINSIC regulator here.

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