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This is only for Mass Spectra interpretation, Mclafferty radical-ion rearrangement:

(aldehyde after bombardment with electrons): {CH3-CH2-CH2-CHO}+ . --> (transformed to alcohol by the movement of the e- from the loss of one H+ from the initial aldehyde molecule and sequential fragmentation): [CHOH=CH2]+ + [H2C=CH2].

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