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Atmospheric pressure at sea level is 14.7 pounds per square inch.
Psia

(pounds per square inch absolute) is also 14.7 pounds per square inch.

However psia starts with zero pounds per square inch at 29.92 in Hg which is a vacuum measurement (absolute vacuum) in inches of Mercury or in Hg.

14.7 psi atmospheric pressure is as high as atmosphere pressure will ever reach. all measurements below that is a vacuum. That is where psia come in. It can start measurements in a vacuum and continue with the same unit of measurement after it comes out of the vacuum at 14.7 psi.

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