The molecular orbital diagram for CO shows the formation of sigma and pi bonding orbitals. The diagram would illustrate the mixing of carbon's 2s and 2p orbitals with oxygen's 2s and 2p orbitals to form molecular orbitals. The diagram would also show the bond order and relative energies of the bonding and antibonding orbitals in CO.
The bond order of helium (He) is 0. In a diatomic helium molecule (He₂), there are two electrons in the bonding molecular orbital and two electrons in the antibonding molecular orbital. The bond order is calculated as (number of bonding electrons - number of antibonding electrons) / 2, which results in (2 - 2) / 2 = 0. Therefore, He₂ does not form a stable bond.
After the 3p orbital, the next atomic orbital is the 4s orbital. In the order of filling according to the Aufbau principle, the 4s orbital is filled before the 3d orbital. Following the 4s, the 3d orbitals are filled, and then the 4p orbitals come next.
Molecular orbital theory predicts that ground state diatomic oxygen has two unpaired electrons (it is a diradical) which occupy its pi orbitals. These unpaired electrons produce a magnetic moment and are responsible for the paramagnetic property of diatomic oxygen.
4s-orbital will be filled prior to 3d-orbital.ORBITALnl(n+l)4s404+0 = 43d323+2 = 5Since 4s-orbital has least value of (n+l), therefore ,it will occupy electrons before3d-orbital.The order of increasing of energy of orbitals can be calc. from(n+l) rule or 'Bohr bury rule' According to this rule, the value of n+l is the energy of the orbital and such on orbital will be filled up first. e.g. 4s orbital having lower value of(n+l) has lower energy than 3d orbital and hence 4s orbital is filled up first. For 4s orbital, n+l=4+0=4 For 3d orbital, n+l=3+2=5,therefore 4s orbital will be filled first.
Some disadvantages of the molecular orbital approach include the complexity of calculations involved, especially for larger molecules, as well as difficulties in accurately predicting electronic interactions in systems with strong electron correlation. Additionally, the interpretation of molecular orbital diagrams can sometimes be challenging for non-experts due to the abstract nature of the theory.
molecular theory explains weather a molecule will exist or not on the basis of bond order. that is by taking difference of bonding and antibonding electrons.this seems good for diatomic molecule but fails for polyatomic molecule. for example, take He3 molecule. according to molecular orbital theory the bond order comes out to be one which implies that the molecule must exist and must have a single bond in it. but no such molecule exist practically.
The molecular orbital diagram for CO shows the formation of sigma and pi bonding orbitals. The diagram would illustrate the mixing of carbon's 2s and 2p orbitals with oxygen's 2s and 2p orbitals to form molecular orbitals. The diagram would also show the bond order and relative energies of the bonding and antibonding orbitals in CO.
Molecular Orbital Theory (MOT):•Basic idea of MOT is that atomic orbitals of individual atoms combine toform molecular orbitals. Electrons in molecule are present in themolecular orbitals which are associated with several nuclei.•The molecular orbital formed by the addition of atomic orbitals is calledthe bonding molecular orbital (s ).•The molecular orbital formed by the subtraction of atomic orbital is calledanti-bonding molecular orbital (s*).•The sigma (s ) molecular orbitals are symmetrical around the bond-axiswhile pi (p ) molecular orbitals are not symmetrical.•Sequence of energy levels of molecular orbitals changes for diatomicmolecules like Li2, Be2, B2, C2, N2 is 1s < *1s < 2s< *2s < ( 2px = 2py)
After the 3p orbital, the next atomic orbital is the 4s orbital. In the order of filling according to the Aufbau principle, the 4s orbital is filled before the 3d orbital. Following the 4s, the 3d orbitals are filled, and then the 4p orbitals come next.
The bond order of PO is 1.5. This is calculated by taking the difference between the number of bonding and antibonding electrons and dividing by 2 in the molecular orbital diagram of the molecule.
The expected bond order for diatomic B2 is 1, calculated by subtracting the number of antibonding electrons from the number of bonding electrons in the molecular orbital diagram.
Molecular orbital theory predicts that ground state diatomic oxygen has two unpaired electrons (it is a diradical) which occupy its pi orbitals. These unpaired electrons produce a magnetic moment and are responsible for the paramagnetic property of diatomic oxygen.
Order theory is the theory that society is based on shared values. That society is explained by the values they hold and defend. According to this theory, the reason discrimination occurs is that the society is defending its values from the 'intruding' value set that the immigrated have brought with them.
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The bond order of NO+ is 2.5, which indicates a bond that is between a single and a double bond. This is because there are 11 valence electrons shared between the nitrogen and oxygen atoms, giving rise to a half-filled molecular orbital.
4s-orbital will be filled prior to 3d-orbital.ORBITALnl(n+l)4s404+0 = 43d323+2 = 5Since 4s-orbital has least value of (n+l), therefore ,it will occupy electrons before3d-orbital.The order of increasing of energy of orbitals can be calc. from(n+l) rule or 'Bohr bury rule' According to this rule, the value of n+l is the energy of the orbital and such on orbital will be filled up first. e.g. 4s orbital having lower value of(n+l) has lower energy than 3d orbital and hence 4s orbital is filled up first. For 4s orbital, n+l=4+0=4 For 3d orbital, n+l=3+2=5,therefore 4s orbital will be filled first.