answersLogoWhite

0

CO is not a homo-nuclear atom like C2, N2 or even O3, O3 (both these categories are different: with and without 2s-2p mixing).

So there is a large discrepancy in the atomic energy levels of 2s, 2p e- of C and O.As a result, 2p(pi)x, 2p(pi)y and 2p(sigma)z have lower energy than 2s(sigma)*. So the e- lost is from 2s(sigma)*2 and not 2p(sigma)z.

And hence the bond order increases from 3 to 3.5 and not decreases to 2.5 .

(The typical school textbook formula doesn't work for species like CO,CO+ and even NO,NO+ in many situations):-)

User Avatar

Wiki User

13y ago

What else can I help you with?