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Phosphorus electron strucure is [Ne] 3s2 3p3,

To form a noble gas configuration of Argon: [Ne] 3s2 3p6, Phosphorus has to 'pick up' 3 electrons, but this is only 'done' in covalent bonding to Hydrogen (H3P) or alkali metals (forming of phosphides); the independent, pure ionic form of P3- does not exist.

To form a noble gas configuration of Neon: [1s2, 2s2 2p6] 3s0 3p0, Phosphorus has to 'donate' 5 electrons, but this is only 'done' in polar-covalent bonding to Oxygen; also the independent, pure ionic form of P5+ does not exist.

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