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When Pluto has an atmosphere, at its closest approach to the Sun, this thin layer is comprised of nitrogen, methane, and carbon monoxide. The problem with percentages is that it changes constantly. The irregular heating of the surface, the greenhouse nature of methane that causes inversion layers, and the sheer distance Pluto is from our ability to observe it make determining the average level of any of these three gases extremely difficult at best. We didn't even know for certain until 1985 that Pluto even had an atmosphere.

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