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The size of d orbitals generally increases with the principal quantum number (n) and the number of electrons in the orbitals. In the context of silicon (Si), phosphorus (P), sulfur (S), and chlorine (Cl), these elements primarily utilize s and p orbitals in their bonding, as they are located in the second and third periods of the Periodic Table. However, if we consider the energy levels and trends, the size of d orbitals would follow the order of increasing atomic number, with phosphorus having the lowest energy d orbitals, followed by sulfur, chlorine, and then silicon, which has no d orbitals in its ground state. Thus, the order would not directly apply to these elements since Si, P, S, and Cl have no d orbitals in their valence shells.

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