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The pulmonary artery is the blood vessel that leads away from the heart (Artery=Away), toward the lungs. It is pumping blood to that lungs that just returned from the body (via the vena cava, into the right atrium). So the blood in the pulmonary artery has the lowest concentration of O2 and the highest concentration of CO2. It is just about to pick up lots of oxygen, once it gets to the lungs.

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