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The first atmosphere would have consisted of gases in the solar nebula, primarily hydrogen. In addition there would probably have been simple hydrides such as are now found in gas-giant planets like Jupiter and Saturn, notably water vapor, methane and ammonia.

The next atmosphere, probably consisting largely of nitrogen (partly in the form of ammonia), carbon dioxide,water vapor and other gases, but no free oxygen. This amosphere was produced by outgassing from volcanism, supplemented by gases produced during the late heavy bombardment of Earth by huge asteroids.

Free oxygen did not exist until about 1.7 billion years ago (thank you plants).

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