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"When the Sun runs out of hydrogen to fuse, the balance tips in the favor of gravity, and the star starts to collapse. But compacting a star causes it to heat up again and it is able fuse what little hydrogen remains in a shell wrapped around its core. This burning shell of hydrogen expands the outer layers of the star. When this happens, our Sun will become a red giant; it will be so big that Mercury will be completely swallowed! When a star gets bigger, its heat spreads out, making its overall temperature cooler. But the core temperature of our red giant Sun increases until it's finally hot enough to fuse the helium created from hydrogen fusion. Eventually, it will transform the helium into carbon and other heavier elements. The Sun will only spend one billion years as a red giant, as opposed to the nearly 10 billion it spent busily burning hydrogen. We already know that medium mass stars, like our Sun, become red giants. But what happens after that? Our red giant Sun will still be eating up helium and cranking out carbon. But when it's finished its helium, it isn't quite hot enough to be able to burn the carbon it created. What now? Since our Sun won't be hot enough to ignite the carbon it its core, it will succumb to gravity again. When the core of the star contracts, it will cause a release of energy that makes the envelope of the star expand. Now the star has become an even bigger giant than before! Our Sun's radius will become larger than Earth's orbit! The Sun will not be very stable at this point and will lose mass. This continues until the star finally blows its outer layers off. The core of the star, however, remains intact, and becomes a white dwarf. The white dwarf will be surrounded by an expanding shell of gas in an object known as a planetary nebula. They are called this because early observers thought they looked like the planets Uranus and Neptune."

This is taken from http://imagine.gsfc.NASA.gov/docs/science/know_l1/dwarfs.html

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