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In the formate ion (HCOO⁻), the C-O bond lengths are expected to be longer than those in carbon dioxide (CO2). This is due to the resonance structures in formate, which create a distribution of electron density and results in single bond character, while CO2 has two double bonds that are shorter and stronger. Consequently, the presence of a single bond in formate contributes to a longer C-O bond length compared to the double bonds in CO2.

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