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First of all, acknowledge that the charge of one proton (which cannot move) = the charge of an electron (can move). The electrons on that particular atom or object lets say, transfer from itself with the help of extra energy (e.g. friction or mere contact) so then the atom which was once neutral (same number of protons to electrons) and there are more protons than electrons because the electrons just left the atom. This means that there are more positive charges than negative ones, which means there is an overall positive charge, giving a positive electric charge.

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