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Alpha particle is nothing but the He nucleus. He nucleus has two protons and two neturons. So 4 nucleons.

As alpha comes out of the parent nucleus, then the by product ie daughter nucleus would have 2 protons less and 4 nucleons less.

So 88Ra226 after emitting one alpha particle gets changed into 86 Rn 222. Rn is Radon.

So 88Ra226 ----------> 86 Rn 222 + 2 He 4

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