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When the liquid reaches its boiling point, it changes phase into a gas. The energy is being absorbed into breaking of the interparticular bonds. This is called the latent heat of vaporisation.

In a pot of water that is boiling, the water is all at 100 degrees, however, only the water on the surface, or at nucleation sites, is able to change state into a gas. The steam that the water is turning into, is also at 100 degrees.

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