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Maybe the molar ratio of Ca to EDTA at equivalent titration is miscalculated: Not 2 Ca reacts with 1 EDTA (= tetra-acetate) but it is an equi-molar reaction: 1 Ca reacts with 1 EDTA.

Not Ca2Edetate is formed, but rather CaH2Edetate (monocalcium dihydrogen ED-tetra acetate)

If so the EDTA analysis outcome will be halved, so I would more trust on the FPM-outcome 2 ppm

If not, then I really don't know. Try a recalculation, succes.

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13y ago

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